中文摘要:
金属有机分子笼(mocs)在主客体化学、催化、光学生物成像等众多领域表现出潜在的应用价值,从而引起众多科学家的研究兴趣.稀土金属超分子配位体系由于其独特的光学和磁学特点使众多超分子学者关注和研究.基于配体的设计,综述了不同构型的稀土金属有机分子笼的构筑以及它们在光、磁、催化等方面的应用.
中文关键词: 稀土 金属有机分子笼(mocs) 识别 光 磁 催化
doi:10.3969/j.issn.1000-5137.2019.06.006
基金项目: 国家自然科学基金(21671135);国家自然科学基金青年项目(2190010127)
recent advance of rare earth metal organic cages
he jing, jiao jingjing college of chemistry and materials science, shanghai normal university, shanghai 200234, china
abstract:
metal-organic cages(mocs) have been widely investigated for their bionic feature and potential applications(e.g.stabilization of reactive species,catalysis,lighting and biometric imaging).metal-organic cages based on rare earth metals were popular for their fascinating spectroscopic and magnetic properties.in this review,we summarized synthesis of rare earth metal-organic cages with different configuration and their applications in the fields of lighting,magnetism and catalysis.
key words: rare earth metal-organic cages(mocs) recognition lighting magnetism catalysis